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JAEA Reports

Analytical method for chemical compositions of volcanic glasses in Tono Geoscience Center; Quantitative measurements of Major Elements by using EPMA and Minor Elements by LA-ICP-MS

Kagami, Saya; Yokoyama, Tatsunori; Umeda, Koji*

JAEA-Testing 2021-001, 49 Pages, 2021/08

JAEA-Testing-2021-001.pdf:3.86MB

To make a contribution to safety assessment for geological disposal of high level radioactive and/or TRU waste, we need to assess long-term stability of geological environment and predict long-term changes of geotectonic events that will occur in the future, especially for Quaternary period ($$sim$$ 2.6 million years ago-present). In the most case, we investigate chronological data of geological events by radiometric dating. When some geological samples have no objects to which radiometric dating method can be applied (e.g., zircon, biotite, wood fragments and plant residues), we can use tephrochronology, which is geological dating method using each layer of tephra (erupted volcanic ash), for dating of geological layers. This chronological method is essential in Japan, where volcanism is very active. Tephra is usually characterized by petrographic characteristics and/or chemical composition (mainly major elements) of volcanic glasses and/or minerals in tephra. In Tono Geoscience Center (Japan Atomic Energy Agency), we develop an analytical technique of chemical composition including trace elements of volcanic glasses for detailed tephra identification. In this paper, we report a sample preparation procedure and analytical methods of chemical compositions of individual volcanic glass shards by using an electron probe microanalyzer and a laser ablation-inductively coupled plasma-mass spectrometer.

Journal Articles

Isotope hydrograph separation for modeling of runoff mechanisms of atmospherically derived chemical and radioactive pollutants

Matsunaga, Takeshi; Yanase, Nobuyuki; Hanzawa, Yukiko; Tsuzuki, Katsunori; Naganawa, Hirochika

Journal of Water and Environment Technology (Internet), 3(2), p.243 - 252, 2005/00

In a tributary watershed of the Kuji River of Japan, the hydrological components of runoff associated with a rain storm event were investigated using isotope tracers of hydrogen ($$^{2}$$H) and oxygen ($$^{18}$$O) in precipitations and stream water. The runoff was separated into either "old water" (pre-existing in the ground before the storm) and "new water"(from the storm precipitation). It was found that the discharge of several hazardous trace elements (Sb, Cu, Cr) was largely (24-54%) attributable to that of the new water in spite of its small contribution to the total water discharge. These investigations suggest that the new water may play an important role in the migration of atmospherically derived, hazardous trace elements to streams during rain storms.

Journal Articles

Development of in-air micro-PIXE analysis and its application to biological and environmental science

Arakawa, Kazuo

Aisotopu, Hoshasen Riyo Foramu Koen Rombunshu, 5 Pages, 2003/00

no abstracts in English

Journal Articles

Biological application in a super-high-resolution microbeam PIXE project

Kamiya, Tomihiro

Radioisotopes, 50(8), p.42 - 48, 2001/08

no abstracts in English

Journal Articles

Non-destructive trace element analysis

Oshima, Masumi

Look Japan, 5, p.30 - 31, 2000/06

no abstracts in English

JAEA Reports

None

Yamasaki, Shinichi*

JNC TJ8430 2000-005, 159 Pages, 2000/03

JNC-TJ8430-2000-005.pdf:3.95MB

no abstracts in English

Journal Articles

Development of trace element analysis by using multi dimensional analysis

Hatsukawa, Yuichi; Oshima, Masumi; Hayakawa, Takehito; Toh, Yosuke; Shinohara, Nobuo

Hoshaka Bunseki, (10), p.19 - 20, 2000/03

no abstracts in English

JAEA Reports

None

; *; ; ; Takeda, Seiichiro

PNC TN8410 97-104, 56 Pages, 1997/04

PNC-TN8410-97-104.pdf:2.06MB

None

Journal Articles

The Story of a dreamy track in the application of stable isotopes

; ; ; Terunuma, Kuzuo; *; *; *

Antei Doui Genso O Meguru Yume No Kiseki; The Story, p.37 - 60, 1997/00

no abstracts in English

Journal Articles

JAEA Reports

None

Ashida, Takashi

PNC TN8600 94-003, 150 Pages, 1994/08

PNC-TN8600-94-003.pdf:13.42MB

no abstracts in English

Journal Articles

Effect of minor alloying elements on hot-workability of Ni-Cr-W superalloys

Tsuji, Hirokazu; *; *; Nakajima, Hajime

Journal of Nuclear Science and Technology, 31(2), p.122 - 129, 1994/02

 Times Cited Count:3 Percentile:35.79(Nuclear Science & Technology)

no abstracts in English

Journal Articles

Ion microbeam technique and development for its new application

Tanaka, Ryuichi; Kamiya, Tomihiro

Hoshasen, 20(3), p.21 - 32, 1994/00

no abstracts in English

JAEA Reports

None

; *; Ouchi, Yoshifusa; ;

PNC TN8410 90-089, 59 Pages, 1990/10

PNC-TN8410-90-089.pdf:1.38MB

None

Journal Articles

Intra-organic change of trace elements in fetal development; Measurement by neutron activation analysis

Shin, Sumio*; Sato, Kiichi*; Nishida, Hiroshi*; Sakamoto, Shoichi*; Yamabayashi, Hisamichi; Motoki, Ryozo; Terunuma, Kusuo; Yamamoto, Takeo

Igaku No Ayumi, 140(1), p.51 - 52, 1987/01

Trace elements serve as key components of enzyme systems and have especially important correlation with fetal maturity.

Journal Articles

Activation analysis of trace elements eco-system; Mereury and selenium in marine animals

Radioisotopes, 24(3), P. 103, 1975/03

no abstracts in English

Journal Articles

Oral presentation

Trace very light element analysis using soft X-ray emission spectrometry in FE-SEM/EPMA

Takahashi, Hideyuki*; Asahina, Shunsuke*; Murano, Takanori*; Takakura, Yu*; Terauchi, Masami*; Koike, Masato; Imazono, Takashi; Koeda, Masaru*; Nagano, Tetsuya*; Sasai, Hiroyuki*; et al.

no journal, , 

We developed a soft X-ray emission spectrometer (SXES) with a detection range of 50-210 eV to be able to be installed in commercially available EMPAs and FE-SEMs. This SXES has the spectral resolution of 0.2 eV comparably high with X-ray photo emission spectrometers (XPSs) and electron energy-loss spectrometers (EELSs). In addition, it allows us to perform trace light element analysis with high sensitivity because of high peak-to-background ratio (P/B). Therefore, it is shown that the SXES installed in a FE-SEM can detect trace carbon in steel at the level of 100 ppm and below.

Oral presentation

Estimation and thermodynamic analysis of natural thorium, uranium, and REE concentrations in groundwater at Horonobe URL

Sasaki, Takayuki*; Kokami, Takayuki*; Amamiya, Hiroki; Murakami, Hiroaki; Amano, Yuki; Iwatsuki, Teruki; Mizuno, Takashi; Kobayashi, Taishi*; Kirishima, Akira*

no journal, , 

For thermodynamic analysis of the trace metals in groundwater, concentrations of Th, U, and rare earth elements (REEs) were investigated at Horonobe Underground Research Laboratory. Groundwater was sampled in anaerobic condition directly from a packed section in the boreholes drilled to 140 m and 250 m depth in drift. The colloidal distribution was checked by an on-site batch ultrafiltration unit using 0.2 $$mu$$m or 10 kDa membranes. As the result, both Th and U concentrations could be estimated by thermodynamic calculations, assuming that the soluble solid phases are restricted to ThO$$_{2}$$(cr) and UO$$_{2}$$(cr), respectively. Meanwhile, the concentrations of REEs were also very low, and significant colloidal distribution for lighter REEs was observed. In the thermodynamic analysis where the lanthanide phosphate was assumed to be a solid phase, the experimental plots matched better with the calculated one, even though the changing trend differs from each other.

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